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Phase Transitions in Polymers: The Role of Metastable States

Stephen Z.D. Cheng




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 | #2405636 in Books |  2008-09-24 | Original language:English | PDF # 1 |  9.21 x.75 x6.14l,1.63 | File type: PDF | 324 pages

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A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are k...

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